A new approach to construct segregated structure in thermoplastic polyolefin elastomer towards improved conductive and mechanical properties - Journal of Materials Chemistry A (RSC Publishing)
Aiming at improved electrical conductive performance and simultaneously enhanced mechanical properties, a novel segregated structure was constructed for poly (ethylene-co-octene) (POE)/multi-walled carbon nanotube (MWCNT) elastomeric conductive composites with chemically cross-linked POE granules. Structural examination revealed the formation of unique phase morphologies with a stable segregated structure, in which the uncross-linked POE/MWCNT phase localized out of the cross-linked granules. With such a novel segregated structure, a percolation threshold as low as 1.5 vol. % of MWCNT was observed, which is significantly lower than the melt compounded POE/MWCNT composites; the stress at 100% and 300% stretching increased for more than 12% and 30%, respectively, and the tensile modulus inherent to the matrix elastomer was maintained. The elastic recovery of the composite with such a novel segregated structure was more than 85% and 65% after large strains up to 100% and 300%, respectively, always higher than the melt compounded POE/MWCNT composites.(...)
